Just a few interesting ones off the top of my head:
Bohol Island, Philippines
Nauto, a village deep in the Peruvian amazon.
Shibu Onsen, Japan
Poon Hill, Penang, Malaysia
A soviet prison (I was born there during the soviet era).
A Ukrainian operating table.
Secret military base in Transnistria.
Quba, Azerbaijan (According to wiki, it's the largest Jewish city outside of Israel).
A military compound in Egypt
Volcán Concepción & Volcán Maderas - Ometepe, Nicaragua
Bob Marleys House/Grave - Jamaica
Rybnitza (Ribnitz) - Transnistria
Swam in a Meromictic lake (GIYF) in Malayisa
Should I keep going?
I have obviously been to 100's of villages, towns & cities that i'm confident no one has been to...