How can I get that? And now long does status match take?
Start with the link to get National Executive status. Ask to status match with Hertz on Twitter (last time was matched pretty much instantaneously). There's a chance they may give you Presidents Circle for that (they officially only match it to Five Star, but it seems like they give PC sometimes). Then status match back to National.
Or you can make another stop first with a program that will give you higher status, so that Hertz will definitely match you to PC